Asymmetric Induction
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Asymmetric induction (also enantioinduction) in stereochemistry describes the preferential formation in a chemical reaction of one enantiomer or diastereoisomer over the other as a result of the influence of a chiral feature present in the substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis. Asymmetric induction was introduced by Emil Fischer based on his work on carbohydrates. Several types of induction exist. Internal asymmetric induction makes use of a chiral center bound to the reactive center through a covalent bond and remains so during the reaction. The starting material is often derived from chiral pool synthesis. In relayed asymmetric induction the chiral information is introduced in a separate step and removed again in a separate chemical reaction. Special synthons are called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand. This method of asymmetric synthesis is economically most desirable.
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GarantieWeitere Informationen
- Allgemeine Informationen
- GTIN 09786130613631
- Editor Frederic P. Miller, Agnes F. Vandome, John McBrewster
- Sprache Englisch
- Genre Chemie
- Größe H220mm x B150mm x T4mm
- Jahr 2010
- EAN 9786130613631
- Format Fachbuch
- ISBN 978-613-0-61363-1
- Titel Asymmetric Induction
- Untertitel Chemical Reaction, Stereochemistry, Enantiomer, Diastereomer, Chirality (Chemistry), Enzyme Substrate, Reagent, Catalysis, Asymmetric Synthesis, Emil Fischer, Carbohydrate, Chiral Pool Synthesis
- Gewicht 118g
- Herausgeber Alphascript Publishing
- Anzahl Seiten 68
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