Catalyst Characterization

to the Fundamental and Applied Catalysis Series Catalysis is important academically and industrially. It plays an essential role in the manufacture of a wide range of products, from gasoline and plastics to fertilizers and herbicides, which would otherwise be unobtainable or prohibitive ly expensive. There are few chemical-or oil-based material items in modern society that do not depend in some way on a catalytic stage in their manufacture. Apart from manufacturing processes, catalysis is finding other important and over-increasing uses; for example, successful applications of catalysis in the control ofpollution and its use in environmental control are certain to in crease in the future. The commercial import an ce of catalysis and the diverse intellectual challenges of catalytic phenomena have stimulated study by a broad spectrum of scientists including chemists, physicists, chemical engineers, and material scientists. Increasing research activity over the years has brought deeper levels of understanding, and these have been associated with a continually growing amount of published material. As recentlyas sixty years ago, Rideal and Taylor could still treat the subject comprehensively in a single volume, but by the 19 50s Emmett required six volumes, and no conventional multivolume text could now cover the whole of catalysis in any depth.

This book presents a comprehensive view of all catalyst characterization techniques. It is unique in offering both spectroscopic and non-spectroscopic techniques. It is also unique in that any reader should be able to find an appropriate characterization technique and example, no matter the situation.

Klappentext

This unique reference critically analyzes the use and application of all major physical methods for determining the structure and behavior of catalysts. Each chapter presents a detailed description of a technique and its theoretical basis, a definition of its field of application, and examples of validity and limitation. Extensive cross referencing between chapters ensures seamless continuity as well as a holistic view of the field.

This new edition covers the substantial progress made since its predecessor in characterization of catalysts.

Inhalt

1. General Introduction.- 2. Infrared Spectroscopy.- 3. Raman Spectroscopy.- 4. Electronic Spectroscopy.- 5. Nuclear Magnetic Resonance in Heterogeneous Catalysis.- 6. Electron Paramagetic Resonance: Principles and Applications to Catalysis.- 7. Ferromagnetic Resonance.- 8. Mössbauer Spectroscopy Nuclear Gamma Resonance.- 9. Auger Electron Spectroscopy.- 10. Vibrational Electron Energy Loss Spectroscopy.- 11. Secondary Ion Mass Spectrometry.- 12. Ion Scattering Spectroscopy.- 13. Applications of Neutron Scattering to Catalysis.- 14. X-Ray Absorption Spectroscopy: Exafs and Xanes.- 15. Determination of the Atomic Structure of Solid Catalysts by X-Ray Diffraction.- 16. Small-Angle X-Ray Scattering.- 17. Photoelectron Spectroscopies: XPS and UPS.- 18. Photoelectron Diffraction and Surface Crystallography.- 19. Characterization of Catalysts by Conventional and Analytical Electron Microscopy.- 20. Applications of Electrical Conductivity Measurements in Heterogeneous Catalysts.- 21. Magnetic Measurements and Catalysis.- 22. Thermal Methods: Calorimetry, Differential Thermal Analysis, and Thermogravimetry.- 23. Mass Spectrometry: Principles and Applications in Catalysis.- 24. Scanning Tunneling and Atomic Force Microscopies.- 25. Final Remarks.