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18-Electron rule
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Details
The 18-electron rule is a rule of thumb used primarily in transition metal chemistry for characterizing and predicting the stability of metal complexes. Valence shells of a transition metal can accommodate 18 electrons: 2 in each of the five d orbitals (10 in total); 2 in each of the three p orbitals (6 in total); and 2 in the s orbital (see Electron counting). In practice, of course, these orbitals cannot directly accept electrons, otherwise one would encounter ions such as Fe10 and Pt8 . However, combination of these atomic orbitals with ligand orbitals gives rise to nine molecular orbitals which are either metal-ligand bonding or non-bonding. (There are also some higher energy anti-bonding orbitals). The complete filling of these nine lowest energy orbitals with electrons, whether those electrons originate from the metal or from any ligands, is the basis of the 18-electron rule. When the metal has 18 electrons, it has then achieved the same electron configuration as the noble gas at the end of the period.
Weitere Informationen
- Allgemeine Informationen
- GTIN 09786130636470
- Editor Frederic P. Miller, Agnes F. Vandome, John McBrewster
- Sprache Englisch
- Genre Physik & Astronomie
- Größe H220mm x B150mm x T6mm
- Jahr 2010
- EAN 9786130636470
- Format Fachbuch
- ISBN 978-613-0-63647-0
- Titel 18-Electron rule
- Untertitel Electron shell, Transition metal, Rule of thumb, Electron, Electron counting, Atomic orbital, Ligand, Noble gas
- Gewicht 153g
- Herausgeber Alphascript Publishing
- Anzahl Seiten 92
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