Peroxodicarbonate

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High Quality Content by WIKIPEDIA articles! In chemistry, peroxodicarbonate is a divalent anion with formula C2O62 . It is one of the oxocarbon anions, that consist solely of carbon and oxygen. Its molecular structure can be viewed as two carbonate anions joined so as to form a peroxide bridge -O-O-. The anion is formed, together with peroxocarbonate CO42 , at the negative electrode during electrolysis of molten lithium carbonate. The anion can also be obtained by electrolysis of a saturated solution of rubidium carbonate in water. Potassium peroxodicarbonate K2C2O6 was obtained by Constam and von Hansen in 1895; its crystal structure was determined only in 2002. It too can be obtained by electrolysis of a saturated potassium carbonate solution at 20°C. It is a light blue crystalline solid that decomposes at 141°C, releasing oxygen and carbon dioxide, and decomposes slowly at lower temperatures.

Weitere Informationen

  • Allgemeine Informationen
    • GTIN 09786131054778
    • Editor Lambert M. Surhone, Miriam T. Timpledon, Susan F. Marseken
    • Genre Chemie
    • EAN 9786131054778
    • Format Fachbuch
    • Titel Peroxodicarbonate
    • Herausgeber Betascript Publishing
    • Anzahl Seiten 104

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