Spectroscopy of Individual Single-Walled Carbon Nanotubes

A thermal chemical vapor deposition (CVD) reactor was built and used to grow vertically and horizontally aligned carbon nanotube arrays. The as-grown nanotubes were investigated on a single tube level using near-infrared photoluminescence (PL) microscopy and PL excitation spectroscopy as well as Raman, atomic force and scanning electron microscopy. The PL of single-walled carbon nanotubes (SWNT) in different surroundings and at temperatures down to 4 K was analyzed. Ultralong CVD-grown nanotubes were imaged on Si/SiO2 to determine their chirality and to check structural integrity along the nanotube length. Furthermore, ultralong SWNTs were manipulated (moved, bent and fractured) employing an AFM. Finally, a new approach to determine relative abundances and PL quantum yields of semiconducting SWNTs in dispersions is presented, which is based on statistical counting of individual nanotubes by means of PL spectroscopy.

Autorentext

studied Chemistry at the KIT and Umass, Amherst (USA) and is currently employed at the "Zentrum für Sonnenenergie- und Wasserstoff-Forschung" in Stuttgart where he is doing research on thin-film photovoltaics using Cu(In,Ga)Se2 Chalcopyrite semiconductors.