Acyclic and Macrocyclic Polypyrazoles: Coordination Chemistry

We demonstrate that macrocyclic pyrazolic compounds are expected to form stable complexes both with transition and alkali metals, while acyclic pyrazole compounds containing one, two, three or four pyrazole rings only form complexes with transition metal cations. They do not complex alkali metal cations at all. This serves to emphasise the novel peculiarity of the ligands containing linked pyrazole groups.

Autorentext

Smaail RADI obtained a Doctorate in Bio-organic Chemistry, and a state Doctorate degree in Physical Organic Chemistry. He is currently Professor of organic, bio-organic and Materials chemistry. He is Director of Laboratory of Applied Chemistry and Environment, Author of about 200 scientific papers and Member of several international collaborations.