Anionic Cycloaddition in the Synthesis of Carbazoles

Over the last few years, a wide range of biologically active carbazole alkaloids have been isolated from plant sources. Many of these natural products manifest a variety of biological activities. In addition to their use in medicinal chemistry, carbazoles have attracted increasing attention from the community of material scientists owing to their potential in photophysical and optoelectronic applications. Polyvinylcarbazole (PVK) has been extensively investigated for its use in photorefractive materials and xerography, while N-ethylcarbazole (ECz) was recognized as an effective charge-transporting functional plasticizer for PVK and other doped polymers. In view of these important applications, we set out to develop an anionic cycloaddition for the carbazole synthesis and to apply the method to the synthesis of naturally occurring carbazoles. The dissertation results should be useful to researchers and especially to students and professionals in organic chemistry, material chemistry or medicinal chemistry fields.

Autorentext

Dr.B.K.Senapati is an Assistant Professor at P. K. College,W.B.,India. He did M. Sc. in 2001 from the Vidyasagar University and Ph.D. from IIT, Kharagpur in 2007. Then he joined to Sungkyunkwan University, Seoul for postdoctoral research. The area of his research interest is natural product synthesis and chiral catalyst development.