Interfaces in New Materials

Thisbookreportstheproceedingsoftheworkshop Interfaces in New Materials organisedbytheMaterialsDivisionoftheInstitutInterfacultairedeSciencesNaturelles AppliqueesandtheCenterforAdvancedMaterialsoftheUniversiteCatholiquede Louvain,heldinNovember1990. Theobjectiveofthisworkshopwastobringtogetherscientistsfromdifferenthorizons whoseareasofresearcharethestudyandthecharacterisationofinterfaces. Three maintopicswereselected:thephysico-chemicalcharacterisation,theroleandthe modificationofinterfaces. Twoinvitedgenerallectures(Prof. M. vandeVoordefromtheJointResearchCentre, Petten,TheNetherlandsandDr. M. CourbierefromtheCentredeRecherchesde Voreppe,France)andtwenty-fourcommunicationsarereportedintheseproceedings. P. GRANGE B. DELMON VII Contents Preface v Understandinginterfaces. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 B. DELMON Developmentsinhightemperaturematerialsjoining. . . . . . . . . . . . . . . . . . . . . . . . . 12 M. VANDEVOORDE &M. G. NICHOLAS Metal-ceramicjoining,animportantkeytoceramicmaterialsdevelopment. . . . . . . . . 29 M. COURBlERE HightemperaturedeformationofAl203/Zr02matrixceramiccomposites: interfacecontrolledcreep 42 R. DUCLOS, R. MARTINEZ &1. CRAMPON FormationofLaA10thickfilmonAl0substrates. . . . . . . . . . . . . . . . . . . . . . . . . 52 3 Z 3 O. STRYCKMANS &P. R. DUVIGNEAUD Interphaseregionincompositesystems:analysis,characterisation andinfluenceonlongtermbehaviour. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 A. H. CARDON,W. P. DEWILDE,M. VERHEYDEN, D. VANHEMELRIJCK,L. SCHll. LEMANS &F. BOULPAEP Wettabilityofaglazeonaceramicsubstrateathightemperature applicationtotheglazingoftheporcelainofLimoges. . . . . . . . . . . . . . . . . . . . . . . 68 J. C. LABBE &V. PAULYOU Chemicalsensorsusinghetero-contactofceramics 76 M. MIYAYAMA,Y. NAKAMURA,H. YANAGIDA & K. KOUMOTO Surfacestudyofnewmicroporouspolymericmembranesusedas asubstratumforanimalcellculture. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84 1. L. DEWEZ, A. DOREN,Y. -J. SCHNEIDER, R. LEGRAS &P. G. ROUXHET Influenceofcarbonfibresurfacecharacteristicsonthemicromechanical behaviourofthecarbon-epoxyinterface. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 M. DESAEGER &I. VERPOEST viii Colloidcoatingsandmaterials. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 P. G. ROUXHET Polycarbonate/polybutyleneterephthalateblends. Controlofthe phasediagrarnme. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120 R. LEGRAS,J. DEVAUX&D. DELIMOY Ultrastructuralaspectsoffibre-matrixbondincellulosecementcomposites 129 B. DELHONEUX,E. BAES&T. AVELLA Roleoftheinterphases intherubberlbrassadhesion. . . . . . . . . . . . . . . . . . . . . . . . 139 F. DELAMARE & R. COMBARIEU Useofionicspectrometriesforthestudyofthemetal/polymerinterface 149 Y. DEPUYDT,P. PHUKU &P. BERTRAND Modificationofthestructureandtextureofinterfacesinthepreparation ofcatalystsandduringcatalysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 T. MACHEJ,M. REMY,P. RUIZ &B. DELMON Pre-oxidizedcopperandaluminabonding. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 C. ESNOUF &D. TREHEUX Microscopicapproachofthemetalinsulatoradhesion 180 G. BORDIER &C. NOGUERA Diffusionbondingbetweeninconel600andalumina 190 B. TANGHE,O. EVRARD,J. P. MEYNCKENS& F. DELANNAY Electronmicroscopyofinterfacesinnewmaterials 200 G. VANTENDELOO,C. GOESSENS,D. SCHRYVERS, J. VANHAVENBERGH,A. DEVEIRMAN &J. VANLANDUYT Wettabilityandadhesionofmetallicliquidsonceramicsinnon-reactive andreactivesystems 210 D. CHATAIN,L. COUDURIER,A. STEINCHEN & N. EUSTATHOPOULOS Wettabilityofrealsurfacesinliquidmetal/monocrystallinealumina andcontactanglehysteresis 219 V. DEJONGHE &D. CHATAIN Interfacialreactionduringactivebrazingprocessonmetal-ceramic (SiC)joints " 229 B. BATFALSKY IX Interfacephenomena,morphologyan

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lsensorsusinghetero-contactofceramics 76 M. MIYAYAMA,Y. NAKAMURA,H. YANAGIDA & K. KOUMOTO Surfacestudyofnewmicroporouspolymericmembranesusedas asubstratumforanimalcellculture. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84 1. L. DEWEZ, A. DOREN,Y. -J. SCHNEIDER, R. LEGRAS &P. G. ROUXHET Influenceofcarbonfibresurfacecharacteristicsonthemicromechanical behaviourofthecarbon-epoxyinterface. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 M. DESAEGER &I. VERPOEST viii Colloidcoatingsandmaterials. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 P. G. ROUXHET Polycarbonate/polybutyleneterephthalateblends. Controlofthe phasediagrarnme. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120 R. LEGRAS,J. DEVAUX&D. DELIMOY Ultrastructuralaspectsoffibre-matrixbondincellulosecementcomposites 129 B. DELHONEUX,E. BAES&T. AVELLA Roleoftheinterphases intherubberlbrassadhesion. . . . . . . . . . . . . . . . . . . . . . . . 139 F. DELAMARE & R. COMBARIEU Useofionicspectrometriesforthestudyofthemetal/polymerinterface 149 Y. DEPUYDT,P. PHUKU &P. BERTRAND Modificationofthestructureandtextureofinterfacesinthepreparation ofcatalystsandduringcatalysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 T. MACHEJ,M. REMY,P. RUIZ &B. DELMON Pre-oxidizedcopperandaluminabonding. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 C. ESNOUF &D. TREHEUX Microscopicapproachofthemetalinsulatoradhesion 180 G. BORDIER &C. NOGUERA Diffusionbondingbetweeninconel600andalumina 190 B. TANGHE,O. EVRARD,J. P. MEYNCKENS& F. DELANNAY Electronmicroscopyofinterfacesinnewmaterials 200 G. VANTENDELOO,C. GOESSENS,D. SCHRYVERS, J. VANHAVENBERGH,A. DEVEIRMAN &J. VANLANDUYT Wettabilityandadhesionofmetallicliquidsonceramicsinnon-reactive andreactivesystems 210 D. CHATAIN,L. COUDURIER,A. STEINCHEN & N. EUSTATHOPOULOS Wettabilityofrealsurfacesinliquidmetal/monocrystallinealumina andcontactanglehysteresis 219 V. DEJONGHE &D. CHATAIN Interfacialreactionduringactivebrazingprocessonmetal-ceramic (SiC)joints " 229 B. BATFALSKY IX Interfacephenomena,morphologyandmicrostructureofthermallysprayed metalandceramiccomposites. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 239 H. -D. STEFFENS&J. DROZA CharacterizationofausteniticstainlesssteelAISI304surfacesby meansofglancingangleX-raydiffraction 253 C. QUAEYHAEGENS,L. M. STALS &M. VANSTAPPEN TheinterfacebetweenTiNcoatingsandAISI304steelsubstrates fordifferentdepositionconditions:Atransmissionelectron microscopystudy. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 262 J. D'HAEN,L. DESCHEPPER,M. VANSTAPPEN &L. M. STALS ConcludingremarksontheworkshopInterfacesinNewMaterials. . . . . . . . . . . . . .

Inhalt
Understanding interfaces.- Developments in high temperature materials joining.- Metal-ceramic joining, an important key to ceramic materials development.- High temperature deformation of Al2O3/ZrO2 matrix ceramic composites: interface controlled creep.- Formation of LaAlO3 thick film on Al2O3 substrates.- Interphase region in composite systems: analysis, characterization and influence on long term behavior.- Wettability of a glaze on a ceramic substrate at high temperature application to the glazing of the porcelain of Limoges.- Chemical sensors using hetero-contact of ceramics.- Surface study of new microporous polymeric membranes used as a substratum for animal cell culture.- Influence of carbon fibre surface characteristics on the micromechanical behaviour of the carbon-epoxy interface.- Colloid coatings and materials.- Polycarbonate/polybutylene terephthalate blends. Control of the phase diagramme.- Ultrastructural aspects of fibre-matrix bond in cellulose cement composites.- Role of the interp…