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Kinetic Isotope Effect
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Details
The kinetic isotope effect (KIE) is a dependence of the rate of a chemical reaction on the isotopic identity of an atom in a reactant. It is also called "isotope fractionation," although this term is somewhat broader in meaning. An isotopic substitution will greatly modify the reaction rate when the isotopic replacement is in a chemical bond that is broken or formed in the rate limiting step. In such a case, the change is termed a primary isotope effect. When the substitution is not involved in the bond that is breaking or forming, a smaller rate change, termed a secondary isotope effect is observed. Thus, the magnitude of the kinetic isotope effect can be used to elucidate the reaction mechanism. If other steps are partially rate-determining, the effect of isotopic substitution will be masked.
Weitere Informationen
- Allgemeine Informationen
- GTIN 09786130270940
- Editor Frederic P. Miller, Agnes F. Vandome, John McBrewster
- Sprache Englisch
- Genre Chemie
- Jahr 2009
- EAN 9786130270940
- Format Fachbuch
- ISBN 978-613-0-27094-0
- Titel Kinetic Isotope Effect
- Untertitel Reaction rate, Chemical reaction, Isotope, Hydrogen, Deuterium, Reaction rate constant, Chemical bond, Rate-determining step, Reaction mechanism, Mass
- Herausgeber Alphascript Publishing
- Anzahl Seiten 140
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