Molecular Constants Mostly from Infrared Spectroscopy

The present subvolume provides evaluated infrared spectroscopic data on O3 (Ozone) and is dedicated to all available molecular constants in the electronic ground state, of the 18 isotopomers. It is made of separate chapters. The first one succinctly reports molecular theories and equations, based on which most of the evaluated data given in the other chapters are established. Title of each data chapter indicates which data is reported (vibrational states, vibrational energy, band centers, harmonic frequencies, anharmonic constants, rotational and centrifugal distortion constants, resonance coupling constants, potential energy function, force constants, dipole transition moment, integrated band intensity, line shape parameters). The isotopic identification, the natural isotopic abundance, and the cited bibliographic references are also given in each data chapter.

Standard reference book with selected and easily retrievable data from the fields of physics and chemistry Data collected by acknowledged international scientists Also available on our online platform SpringerMaterials, http://materials.springer.com

Inhalt
Introduction.- General remarks.- Energy level vibrational assignment. Normal modes and Local modes.- Rotational assignment.- Polyads. Energy level vibrational interactions.- A-reduced Watson-type rotational Hamiltonian.- S-reduced Watson-type rotational Hamiltonian.- Perturbation-theory free, Jensen MORBID Hamiltonian.- Jensen's PES determined by variational calculation of rotationvibration energies, with MORBID Hamiltonian.- Force field parameters.- Dipole moment.- Line profiles.- References.- O3 data.