Roussin's Red Salt
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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Roussin''s Red Salt is the inorganic compound with the formula [K2][Fe2S2(NO)4]. This metal nitrosyl consists of the potassium salt of the [Fe2N4O4S2]2 anion. This compound was first described in 1858 by the French chemist M.L. Roussin while experimenting with reactions between nitroprusside ion, [Fe(CN)5NO]2 , and sulfur, making it the first synthetic iron-sulfur cluster. Roussin''s red salt anion is an example of a ligand-bridged metal dimer. Its structure is described as an edge-shared bitetrahedron, wherein a pair Fe(NO)2 units are bridged by a pair of sulfide ligands. The Fe-NO bonds are linear indicating NO is acting as a three electron donor.
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GarantieWeitere Informationen
- Allgemeine Informationen
- GTIN 09786130916671
- Editor Lambert M. Surhone, Miriam T. Timpledon, Susan F. Marseken
- Genre Chemie
- Größe H220mm x B220mm
- EAN 9786130916671
- Format Fachbuch
- Titel Roussin's Red Salt
- Herausgeber Betascript Publishing
- Anzahl Seiten 80
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