Swain Equation

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High Quality Content by WIKIPEDIA articles! The kinetic isotope effect (KIE) is a dependence of the rate of a chemical reaction on the isotopic identity of an atom in a reactant. It is also called "isotope fractionation," although this term is somewhat broader in meaning.An isotopic substitution will greatly modify the reaction rate when the isotopic replacement is in a chemical bond that is broken or formed in the rate limiting step. In such a case, the change is termed a primary isotope effect. When the substitution is not involved in the bond that is breaking or forming, a smaller rate change, termed a secondary isotope effect is observed. Thus, the magnitude of the kinetic isotope effect can be used to elucidate the reaction mechanism. If other steps are partially rate-determining, the effect of isotopic substitution will be masked.

Weitere Informationen

  • Allgemeine Informationen
    • GTIN 09786131155536
    • Editor Lambert M. Surhone, Miriam T. Timpledon, Susan F. Marseken
    • Genre Chemie
    • EAN 9786131155536
    • Format Fachbuch
    • Titel Swain Equation
    • Herausgeber Betascript Publishing
    • Anzahl Seiten 112

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