Synthesis and Study of Some New Substituted Phthalocyanines

A new substituted phthalocyanines were synthesized from starting materials 4-nitrophthalonitrile and 4-amino phthalonitrile afforded tetra-( (E)-5-(3-(dodec-1-enyl)-2,5-dioxopyrrolidin-1-yl)-2- hydroxybenzoic acid )zinc phthalocyanine (C1), tetra-( (E)-5-(3-(dodec-1-enyl)-2,5-dioxopyrrolidin-1-yl)-2- hydroxybenzoic acid) copper phthalo -cyanine (C2), tetra-( dodecenyl succinicanhydride) zinc phthalocyanine(H1), tetra-(dodecenyl succinic anhydride) copper phthalocyanine (H2) and Azo-dimeric hexasubstituted dodecenyl succinic anhydride nickel-zinc phthalocyanine (F) by Many steps.The newly synthesized compounds have been characterized by elemental analysis, FTIR,1H NMR, UV-Visible and fluorescence spectroscopies techniques.

Autorentext
Assist.Prof.Dr. Mohanad Mousa Kareem,PhD (Glasgow University-UK), MRSC,Organic Chemistry.Languages:English and Arabic